Dr. Michael J. Shaw

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Southern Illinois University Edwardsville
College of Arts and Sciences
Chemistry
ProfessorAppointed: 2008
Professional Headshot of Michael J. Shaw

Mailing Address

Department of Chemistry
Box 1652
Southern Illinois University Edwardsville
Edwardsville, Illinois 62026-1652
United States

Contact Information

Phone: (618) 650-3579
Fax: (618) 650-3556
michsha@siue.edu

Expertise and Research Interests

We have been examining the electrochemical and spectroelectrochemical properties of metal-alkyne complexes. The point of this experiment is to look at the electrode products while they are still in the diffusion layer close to the electrode surface. We use a regular disk electrode suitable for cyclic voltammetry experiments coupled to an mid-IR, near IR, or visible detection system..

A fiber optic cable brings the light beam close to the electrode. The beam passes through the solution, bounces off the reflective electrode surface, and is transmitted through another set of fiber-optics to a liquid-nitrogen cooled detector.

Labview resources generated by my group are available at
http://decibel.ni.com/content/people/roadchem?view=overview

Other Expertise

Synthetic organometallic chemistry, electroanalytical chemistry.

Keywords

COS Keywords:

Electrochemistry, Organometallic Chemistry.

Additional Terms:

Electrochemistry, Organometallic Chemistry, Spectroelectrochemistry.

Memberships

American Chemical Society

Honors and Awards

2006-2008, 2006 Hoppe Research Award, Southern Illinois University Edwardsville, Southern Illinois University, Inorganic Chemistry

Previous Positions

2003-2008, Associate Professor, Southern Illinois University Edwardsville, College of Arts and Sciences, Chemistry
1998-2003, Assistant Professor, SIU Edwardsville, College of Arts and Sciences, Chemistry, Inorganic
1996-1998, Lecturer, University of Vermont, Chemistry
1993-1996, Post-doctoral fellow, University of Vermont, Chemistry

Patents

Compositions and Methods for Relaxing Smooth Muscles, Patent Number: 5631284, 1997, Institution, United States of America.

Funding Received

  • CHE 0821082: MRI: An EPR spectrometer for teaching and research., $174K, 2008 to 2011.
  • CHE 0541546: RUI: The metal-alkyne interaction: Influence on reactivity and physical properties., $214K, 2005 to 2008.
  • CHE 0213297: RUI: Synthesis and Spectroelectrochemistry of Metal Complexes of Acetylenic Ketones and Esters, $229K, 2002 to 2005.
  • Research Corporation: Cottrell College Science Award, $36K, 2000 to 2003.

Publications

  • Michael J. Shaw, William E. Geiger, James E. Eilers (2009) Consequences of the Protonation of the 19-Electron Anion [Co(h5-C5H5)(1,5-C8H12)]-, Organometallics, 28 (18), 5349-5357
  • Carter, S. M., Sia, A., Shaw, M. J., Heyduk, A. F. (2008) Isolation and Characterization of a Neutral Imino-semiquinone Radical, J. Am. Chem. Soc., 130 (18), 5838 - 5839
  • Shaw, M. J., Bryant, S. W, Rath, N. (2007) h1-Vinylidene Formation from Internal Alkynones by C-C Bond Migration, European Journal of Inorganic Chemistry, 2007, 3943-3946
  • Zaki N. Zahran, Michael J. Shaw, Masood A. Khan, George B. Richter-Addo (2006) Fiber-Optic Infrared Spectroelectrochemical Studies of Six-Coordinate Manganese Nitrosyl Porphyrins in Nonaqueous Media, Inorg. Chem., 45 (6), 2661-2668
  • Shawn M. Carter, Jonghyuk Lee, Christopher Adam Hixson, Douglas R. Powell, Ralph A. Wheeler, Michael J. Shaw, George B. Richter-Addo (2006) Fiber-optic Infrared Reflectance Spectroelectrochemical Studies of Osmium and Ruthenium Nitrosyl Porphyrins Containing Alkoxide and Thiolate Ligands, Dalton Transactions, 2006, 1338 - 1346
  • Jelliss, P. A., Mason, J, Nazzoli, J. M, Orlando, J. H., Vinson, A., Rath, N. P., Shaw, M. J (2006) Synthesis and Characterization of Ruthenacarborane Complexes Incorporating Chelating N-Donor Ligands: Unexpected Luminescence from the Complex [k-3-CO-3,3-{2-Me2N(CH2)2NMe2}-closo-3,1,2-RuC2B9H11], Inorg. Chem., 45 (1), 370
  • Michael J. Shaw (2006) Vanadium Electrochemistry In Bard, Allen J., Stratmann, Martin, Scholz, Fritz, Pickett, Christopher J. (eds), Encyclopedia of Electrochemistry, Volume 7, 1 Edition, Weinheim, Wiley-VCH, 357-381 pages, ISBN=3-527-30399-5 (bookchapter)
  • Shaw, M. J., Hyde, J., White, C., Geiger, W. E (2004) Electron-Transfer Induced Tub to Chair Isomerization of the Cyclooctatetraene Ligand in Rh(h5-C5Ph5)(h4-C8H8), Organometallics, 23, 2205
  • Shaw, M. J., Afridi, S. J., Light, S. L., Mertz, J. N., Ripperda, S. E. (2004) Synthesis and Electrochemistry of Iron-Pyrylium Complexes, Organometallics, 23, 2778
  • Ohs, A. C., Rheingold, A. L., Shaw, M. J., Nataro, C. (2004) The Electrochemistry of Group VI Metal Carbonyl Compounds Containing 1,1'-bis(diphenylphosphino)ferrocene., Organometallics, 23, 4655
  • Shaw, M. J., Mertz, J. (2002) Electrocatalytic Reactions of a Manganese-Pyrylium Complex., Organometallics, 21, 3434
  • Shaw, M. J., Henson, R. L., Houk, S. E., Westhoff, J. W., Richter-Addo, G. B., Jones, M. W. (2002) Fiber-Optic IR Reflectance Spectroelectrochemistry: Isomerization of a Manganese Pyranyl Complex, J. Electroanal. Chem., 534, 47
  • Shaw, M. J., Geiger, W. E., Hyde, J., White, C. (1999) 16-Electron Through 19-Electron Complexes of the 1,5-COD and 1,3-COD Isomers of (h5-C5Ph5)Rh(h4-C8H12): Electrochemical Evidence for an Oxidatively-Induced Agostic Interaction, Organometallics, 17, 5486
  • Geiger, W. E., Shaw, M. J., Weunsch, M., Barnes, C. E. (1998) Comparison of Isomerization Rates of the Metal Carbonyl Cluster Cp*IrCp2Co2(CO)3 in Three Oxidation States (47e, 48e, 49e): Dramatic Rate Enhancements in the Odd-Electron Species, J. Am Chem. Soc, 119, 2804
  • Geiger, W. E., Shaw, M. J. (1996) A New Approach to Infrared Spectroelectrochemistry Using a Fiber-Optic Probe: Application to Organometallic Redox Chemistry, Organometallics, 15, 13
  • Legzdins, P., McNeil, W. S., Shaw, M. J., Batchelor, R. J., Einstein, F. W. B. (1995) Characteristic Physical and Chemical Properties of the 17-Valence-Electron Alkyl Complexes CpCr(NO)(L)R., Organometallics, 14, 4751
  • Connelly, N., Geiger, W. E., Lagunas, M. C., Metz, B., Rieger, A. L., Rieger, P. H., Shaw, M. J. (1995) Electron-Transfer-Induced Interconversion of Alkyne and Vinylidene Chromium Complexes: A Quantitative Study, J. Am Chem. Soc., 117, 12202
  • Legzdins, P., McNeil, W. S., Shaw, M. J. (1994) Synthesis, Characterization and Redox Properties of the 17-Valence-Electron Complexes Cp'Cr(NO)(L)X, Organometallics, 13, 562
  • Legzdins, P., Shaw, M. J. (1994) Alkyl-for-Iodide Metathesis Initiated by Dissociation of the Phosphine Ligand from CpCr(NO)(PPh3)I, J. Am. Chem. Soc., 116, 7700
  • Legzdins, P., Shaw, M. J., Reiner, R., Batchelor, R. J., Einstein, F. W. B. (1993) Tetraphenylcyclopentadienyl Nitrosyl Complexes of Molybdenum and Tungsten, Organometallics, 12, 1029
  • Herring, F. G., Legzdins, P., McNeil, W. S., Shaw, M. J., Batchelor, R. J., Einstein, F. W. B. (1991) An Unusual 17-Electron Organometallic Radical CpCr(NO)(PPh3)CH2SiMe3, J. Am. Chem. Soc., 113, 7049

Profile Details

Last Updated: 10/22/2009

COS Expertise ID #1232379
Reference this profile directly: http://myprofile.cos.com/michsha